Explain Ist law of thermodynamics. Prove that internal energy is a property.
[7 marks]Define thermodynamic system. Classify it with proper examples.
[7 marks]Write Kelvin-Planck’s and Clausius’ statements for IInd law of thermodynamics. Prove that violation of Kelvin-Plank statement leads to violation of Clausius statement.
[7 marks]Derive steady flow energy equation. Reduce it for nozzle clearly stating assumptions.
[7 marks]An M.S. steel piece of 5 kg mass is heated to 115° Cand dropped into an insulated vessel containing 30 kg of water at 20° C. due to heat transfer between hot M.S. piece and water, temperature of water rises by 3.5° C. Calculate specific heat of M.S. piece. Take specific heat of water = 4.18 kJ/kg C.
[7 marks]A 3 kg Aluminum block at 200° C & 1 kg of copper block at 100° Care brought into contact but kept isolated from surrounding. Find change in entropy for both blocks and total entropy change when both attain same temperature. Take Cp for Al = 0.9 kJ/kg Kand Cp for Copper = 0.4 kJ/kg K.
[7 marks]Prove that all reversible engines working between two constant temperature reservoirs have the same efficiency.
[7 marks]State the principle of increase of entropy. List the four application of entropy principle.
[7 marks]An engine manufacturer claims to have developed a heat engine with following conditions; Power developed = 75 kW, Fuel burnt = 5 kg/hour, heating value of fuel = 73000 kj/kg, Temperature limits = 1000 Kand 400 K. Is the claim is true or false? Give reason for your answer.
[7 marks]Explain Rankine cycle with necessary diagrams.
[7 marks]Derive equation for exergy of finite heat capacity source at temperature ‘T’. Also differentiate between available and unavailable energy.
[7 marks]Compare Otto, Diesel and Dual cycle for
[7 marks]Same compression ration and heat supplied with necessary diagrams.
[ marks]Explain ideal regenerative cycle. Explain why it is impractical in practice?
[7 marks]Derive Maxwell’s equations.1
[7 marks]State and explain the Gibbs-Dalton law of partial pressures.
[7 marks]With neat sketch, explain the working of Junker’s gas calorimeter.
[7 marks]Derive Vander Waal’s equation.
[7 marks]