What are the different methods for testing kinetic mode? Explain one method.
[3 marks]Write and explain material and energy balance equation with chemical reaction.
[4 marks]Derive the design equation of the ideal batch reactor.
[7 marks]Differentiate between elementary and non-elementary reactions
[3 marks]Explain the size comparison of single ideal CSTR with PFR and mention the different parameter affecting the sizes of the reactor.
[4 marks]Define ideal reactors. Explain the importance of reactor design with broad classification of reactor types.
[7 marks]Find the overall order of the irreversible reaction 2H +2NO N +2H O222 From the following constant volume data using equimolar amount of hydrogen and nitric oxide. Total Press., mm Hg 200 240 280 320 360 Half-life, Sec 265 186 115 104 67
[7 marks]Explain in detail free radicals reaction mechanism.
[3 marks]Continuous stream of gaseous enters a vessel at temperature T =4000 K, P =4 atm, reacts there and leaves at T=300 K, P=3 atm and0 C =100, C =200, A+B--→2R find X , X . AO BO A B
[4 marks]What are the different ideal reactors? Derive the performance equation of Ideal Plug flow reactor (PFR).
[7 marks]Define and Explain single and multiple reactions.
[3 marks]Define recycle ration. Derive the performance equation of recycle reactor.
[4 marks]Find the conversion after 1 hr. in a batch reactor for A--→R, - r =3C 0.5 mol/lit-hr and C =1 mol/l. A A A0
[7 marks]Differentiate between rate of reaction and order of the reactions.
[3 marks]Derive the rate expression for first order irreversible reaction.1
[4 marks]Explain the temperature dependency term in the rate equation using thermodynamics and collision theory.
[7 marks]Write short notes on Activation Energy
[3 marks]What is instantaneous yield and over all fractional yield of the reaction.
[4 marks]Derive the performance equation of steady state Mixed Flow Reactor for the first order reaction with change in density case.
[7 marks]Define and Explain Molecularity and order of reaction
[3 marks]Derive the performance equation of Ideal Mixed Flow Reactor (MFR).
[4 marks]The activation energy of a chemical reaction is 17982 cal/mol in the absence of a catalyst, and 11980 cal/mol with a catalyst. By how much times will the rate of the reaction will grow in the presence of catalyst, if a reaction proceeds at 25 0C
[7 marks]Define and Explain Space time and Space Velocity
[3 marks]Show that total volume required is minimum when two equal sizes CSTR is connected in series.
[4 marks]Substance Areacts according to second-order kinetics. 95% conversion of Ais achieved in a single flow reactor. We buy a second reactor identical to the first. For the same 95% conversion, by how much is the capacity increased if we operate these two Plug flow reactor in series.
[7 marks]