Explain Rand Sconfiguration of lactic acid.
[3 marks]Draw a neat schematic diagram of Polari meter and explain how it works?
[4 marks]What do you understand by S 1 and S 2 reactions? Explain each one with N N Suitable illustration.
[7 marks]Write application of X-ray diffractometer in detail.
[3 marks]Explain Beer-Lambert’s law.
[4 marks]With a neat diagram explain the working of scanning Electron Microscope(SEM).State its application.
[7 marks]Derive Bragg’s equation. How is it used to determine the internal crystal structure?
[7 marks]Explain the following:
[3 marks]Specific rotation (ii) Free radical (iii) Chiral carbon
[ marks]Discuss the optical activity and isomerism in tartaric acid.
[4 marks]With a neat diagram explain the working of Transmission Electron Microscope(TEM).State its application.
[7 marks]What is Mass spectroscopy? State its application.
[3 marks]Explain with the help of MO theory, the paramagnetic character of oxygen.
[4 marks]State Hess’s Law of constant heat, Explain its some important application.
[7 marks]What is the difference between osmosis and diffusion?
[3 marks]Explain bond fission and its type with suitable examples.
[4 marks]Explain the term osmotic pressure. How is the osmotic pressure of a solution is affected by concentration of a solute and by temperature?
[7 marks]Explain the relative stability of primary, secondary carbon ions.
[3 marks]Write a note on Racemization and Asymmetrical synthesis.
[4 marks]What do you understand by reaction intermediate? Explain with suitable example.
[7 marks]Derive Gibbs phase rule thermodynamically.
[3 marks]Discuss about conformational isomerism in cyclohexane.
[4 marks]Discuss the main features of the phase diagram of water system, explaining especially why the slope of solid-liquid line is negative for water?
[7 marks]What are insulating materials?
[3 marks]What are the physical and chemical properties of refractories?
[4 marks]State the basic raw material used in ceramics and explain how chemical conversion take place?
[7 marks]