Show the measurement of Boiling point Elevation.
[3 marks]Define: Optical activity & Specific rotation. Order of reaction, Reaction rate.
[4 marks]Explain the principle, instrumentation of Nuclear magnetic resonance spectroscopy.
[7 marks]Explain the R, S System for Asymmetric Molecules.
[3 marks]Define Term: Normality, Viscosity, Carbenes, Homolytic fission.
[4 marks]Give the types of Organic reaction and discuss Nucleophillic Substitution (SN2) reaction.
[7 marks]Describe Heisenberg Uncertainty Principle
[3 marks]Discuss SP3 Hybridization with suitable example.
[4 marks]Explain the Molecular Orbital Theory.
[7 marks]Give the application of XRD.
[3 marks]The heat of combustion of ethylene at 17° Cand at constant volume is -332.19 kcal. Calculate the heat of combustion at constant pressure considering water to be in liquid state. (R = 2 cal degree-1 mol-1).
[4 marks]Draw the phase diagram of Zinc-Cadmium system. Describe its importance.
[7 marks]Elaborate zero order reaction with suitable example.
[3 marks]Define: Degree of freedom, Eutectic point, heat of combustion, Endothermic reaction.
[4 marks]Draw the phase diagram of one component system and discuss its salient features.
[7 marks]Discuss Pseudo order reaction.
[3 marks]Asolution of H Owhen titrated against KMnO solution at different time224 intervals gave the following results: T(minutes) 0 10 Vol. of KMnO 4 23.8 ml 14.7 ml 9.1 ml used for ml H O22 Selecting the above data, Show that the decomposition of H Ois a first order22 reaction.
[10 marks]Explain mathematical expression for the rate constant of the second order reaction.1
[7 marks]What is the role of reinforcement in composites?
[3 marks]Discuss the classification of ceramics with their general properties.
[4 marks]Describe the each section of Scanning Electron Microscope.
[7 marks]What are copolymers? Give its uses.
[3 marks]Write a note on refractories with their uses.
[4 marks]Explain with principle, instrumentation of mass spectroscopy.
[7 marks]